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Line strengths of the ν 3 - ν 4 band of methane

Identifieur interne : 003D46 ( Main/Exploration ); précédent : 003D45; suivant : 003D47

Line strengths of the ν 3 - ν 4 band of methane

Auteurs : J. C. Hilico [France] ; M. Loete [France] ; Linda R. Brown [États-Unis]

Source :

RBID : ISTEX:BD501F0116B09E2CFFE7050A3589EFE9CB32B4C0

Abstract

Strengths of 413 lines of the ν3 - ν4 band of methane from 1568 to 1932 cm−1 have been measured with 2 to 4% accuracies using spectra recorded at 0.011 cm−1 (unapodized) resolution. Transition strengths up to J3 = 14 have been fitted with a standard deviation of 4% using a four-term, first-order expansion of the dipole moment. A band strength of 0.050(2) cm−2 atm−1 at 296 K is reported for ν3 - ν4 of 12CH4. Estimated band strengths of ν1 - ν4, ν3 - ν2, ν3 + ν4, ν1 + ν4, and ν2 + ν3 are also given.

Url:
DOI: 10.1016/0022-2852(85)90075-X


Affiliations:


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