Line strengths of the ν 3 - ν 4 band of methane
Identifieur interne : 003D46 ( Main/Exploration ); précédent : 003D45; suivant : 003D47Line strengths of the ν 3 - ν 4 band of methane
Auteurs : J. C. Hilico [France] ; M. Loete [France] ; Linda R. Brown [États-Unis]Source :
- Journal of Molecular Spectroscopy [ 0022-2852 ] ; 1984.
Abstract
Strengths of 413 lines of the ν3 - ν4 band of methane from 1568 to 1932 cm−1 have been measured with 2 to 4% accuracies using spectra recorded at 0.011 cm−1 (unapodized) resolution. Transition strengths up to J3 = 14 have been fitted with a standard deviation of 4% using a four-term, first-order expansion of the dipole moment. A band strength of 0.050(2) cm−2 atm−1 at 296 K is reported for ν3 - ν4 of 12CH4. Estimated band strengths of ν1 - ν4, ν3 - ν2, ν3 + ν4, ν1 + ν4, and ν2 + ν3 are also given.
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DOI: 10.1016/0022-2852(85)90075-X
Affiliations:
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<front><div type="abstract" xml:lang="en">Strengths of 413 lines of the ν3 - ν4 band of methane from 1568 to 1932 cm−1 have been measured with 2 to 4% accuracies using spectra recorded at 0.011 cm−1 (unapodized) resolution. Transition strengths up to J3 = 14 have been fitted with a standard deviation of 4% using a four-term, first-order expansion of the dipole moment. A band strength of 0.050(2) cm−2 atm−1 at 296 K is reported for ν3 - ν4 of 12CH4. Estimated band strengths of ν1 - ν4, ν3 - ν2, ν3 + ν4, ν1 + ν4, and ν2 + ν3 are also given.</div>
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